Mscl is the compound obtained when the hydroxy group in the molecule of methanesulfonic acid is replaced with a chlorine atom. Our msds database is an easy to use, do it yourself tool, and best of all. Sodium triacetoxyborohydride is presented as a general reducing agent for the reductive amination of aldehydes and ketones. The free energy, enthalpy, entropy, and heat capacity of activation were calculated. Buy methanesulfonyl chloride d3,c cas 1216581019, a biochemical for proteomics research, from santa cruz. Trichloromethyl methyl sulfide d 3 was found to be one of the intermediates in this reaction. Using the organic pseudoelement symbol ms for the methanesulfonyl or mesyl group ch 3 so 2, it is frequently abbreviated mscl in reaction schemes or equations.
Listing here the database of methanesulfonyl chloride cas no 124630, methanesulfonyl chloride manufacturers, suppliers and exporters. Methanesulfonyl chloride can be used for the mesylation of primary alcohols to synthesize the corresponding methanesulfonates. Procedures for using this mild and selective reagent have been developed for a wide variety of substrates. It is a colourless liquid that dissolves in polar organic solvents but is reactive. In the case of contact with eyes, rinse immediately with plenty of water and seek medical. Als environmental provides no warranty, expressed or implied, as to the accuracy, reliability or. For a more comprehensive list of citations to this article, users are encouraged to perform a search inscifinder. It is a colourless liquid that dissolves in polar organic solvents but is reactive toward water, alcohols, and many amines. Methanesulfonyl chloride msc1 is a versatile reagent that can be used to introduce mesyl groups ch3so22 via.
Sultams obtained as a mixture of two isomers are separable by silica gel column. Methanesulfonyl azide 1516707 chemical cloud database. I have just modified one external link on methanesulfonyl chloride. Articles of methanesulfonyl chloride are included as well. Ungraded products supplied by spectrum are indicative of a. Methane is transformed selectively to methanesulfonyl chloride at low temperature by liquidphase reaction of methane with so 2cl 2 in the presence of a free radical initiator and a promoter using 100%. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. If the file has been modified from its original state, some details such as the timestamp may not fully reflect those of the original file. These methanesulfonyl chloride manufacturing companies are delivering best quality products to the clients on time. Sep 11, 2014 register now and get a free online msds binder.
These methanesulfonyl chloride manufacturing companies. Experimental work at argonne national laboratory has determined that there is essentially no hcl gas formation. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Rates of solvolysis of methanesulfonyl chloride and benzenesulfonyl chloride have been determined in h2o and d2o. Safety data sheet methanesulfonyl chloride date prepared. Ac125640000, ac125640010, ac125640050, ac12564, ac125642500 synonyms. Methanesulfonyl chloride prices,suppliers methanesulfonyl. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Structure, properties, spectra, suppliers and links for. Material safety data sheet benzylamine min 98% msds section 1. Methanesulfonyl chloride cas no 124630 manufacturers. Methanesulfonyl chloride reacts vigorously with water, steam, alkali, methylformamide. Buy methanesulfonyl chlorided3,c cas 1216581019, a biochemical for proteomics research, from santa cruz. Product name methanesulfonyl chloride sigmaaldrich.
Chemical product and company identification product name. Pdf heat capacity of activation for the hydrolysis of. Russo b a lstituto di ricerche sulla combustione, cnr, universit6 di napoli, p. Information for methanesulfonyl chloride 124630 including methanesulfonyl chloride cas no 124630, methanesulfonyl chloride suppliers, methanesulfonyl chloride manufacturers, related products of. Methanesulfonic acid chloridecas no124630molecular formula.
Sciencemadness discussion board methanesulfonic acid. One reagent lane fair lawn, nj 07410 for information in north america, call. Methanesulfonyl chloride using the organic pseudoelement symbol ms for the methanesulfonyl or mesyl group ch3so2, it is frequently abbreviated mscl in reaction schemes or equations. In case of more serious fires, also alcoholresistant foam and water spray. Methanesulfonyl chloride 124630 m2020 spectrum chemical. Methanesulfonyl chloride can be used as catalyst, chlorinating agent, firming agent, stabilizer or as an intermediate for dyes, pharmaceuticals and pesticides. This msds has been prepared according to the hazard criteria of the controlled products regulations cpr and the msds contains all of the information required by the cpr.
This structure is also available as a 2d mol file or as a computed 3d sd file the 3d structure may be viewed using java or javascript. Methanesulfonyl chloride, methanesulfonyl chloride supplier, methanesulfonyl chloride distributor, cas 124630, methanesulfonyl chloride manufacturer, methanesulfonyl chloride wholesale. It may also be used for the conversion of amines to the corresponding sulfonamides. The spill is neutralized after no bubbles are produced. Your new online msds binder is a place for you to store the material safety data sheets. Information for methanesulfonyl chloride 124630 including methanesulfonyl chloride cas no 124630, methanesulfonyl chloride suppliers, methanesulfonyl chloride manufacturers, related products of methanesulfonyl chloride. Methanesulfonyl chloride, also known as mesyl chloride, can be used to generate the elusive molecule sulfene and to make methanesulfonates. Buy 3chloro phenyl methanesulfonyl chloride cas 24974730, a biochemical for proteomics research, from santa cruz.
Synthesis of methanesulfonyl chloride msc from methane and. This file contains additional information such as exif metadata which may have been added by the digital camera, scanner, or software program used to create or digitize it. Development and validation of a gcms with sim method for. Methanesulfonyl chloride supplier distributor cas 124630. Ungraded products supplied by spectrum are indicative of a grade suitable for general industrial use or research purposes and typically are not suitable for human consumption or therapeutic use. Mesyl chloride, methyl sulfonyl chloride cas number 124630. Methanesulfonyl chloride mesyl chloride is an organosulfur compound with the formula ch 3 so 2 cl. The reaction of methanesulfonyl chloride with alcohols in the. Better yields are obtained using a t butylimine 83% than an aryl imine 1859% equation 14. The reaction mixture was stirred at 0 c for 30 min, then was allowed to warm to rt over 2 h. The reaction of methanesulfonyl chloride with alcohols in. Alcohol to mesylate methanesulfonyl chloride meso2cl. This does not prevent hcl formation by a catalytic mechanism, but under normal conditions methanesulfonyl chloride is quite unreactive argonne report anldis001, october 2000.
Methanesulfonyl chloride or mesyl chloride abbreviation. Methanesulfonyl chloride 124630 msds, safety technical. Methanesulfonyl chloride 124630 msds report, methanesulfonyl chloride msds safety technical specifications search, methanesulfonyl chloride safety information specifications ect. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Emits toxic fumes of chloride and oxides of sulfur when heated to decomposition. Sds of methanesulfonyl chloride, safety data sheets, cas 124630. Citation data is made available by participants in crossrefs citedby linking service. Methanesulfonyl chloride is used as a reagent for conversion of alcohols to mesylate esters such as methanesulfonate, which is an intermediate in substitution reactions, elimination reactions, reductions, and rearrangement reactions viz. Show this safety data sheet to the doctor in attendance.
Groups of five male and five female spraguedawley rats were exposed to methanesulfonyl chloride at 0, 20, 28, or 54 ppm analytic concentrations for 4 h, followed by a 14day. Methanesulfonyl chloride revision date 26jan2018 general advice immediate medical attention is required. If you have any questions, or need the bot to ignore the links, or the page altogether, please visit this simple faq for additional information. Development and validation of a gcms with sim method for the. Methanesulfonyl chloride mesyl chloride is a compound containing asulfonyl chloride used to make methanesulfonates and to generate sulfene. Weve included the most sought after safety data sheets, and the database just keeps growing.
External links modified january 2018 hello fellow wikipedians, i have just modified one external link on methanesulfonyl chloride. Methane is transformed selectively to methanesulfonyl chloride at low temperature by liquidphase reaction of methane with so 2cl 2 in the presence of a free radical initiator and a promoter using 100% h 2so 4 as the solvent. Accidental release measures if a spill or leak occurs. Thermokinetic investigation of methanesulfonyl chloride. Methanesulfonyl chloride is the reagent used to convert alcohols into alkyl mesylates. Methanesulfonyl chloride information about methanesulfonyl chloride is for educational purposes only. Cas 124630, ec number 2047061, chemical formula ch. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi.
Methanesulfonyl chloride an overview sciencedirect topics. Un3246 poison chemical information, properties, structures, articles, patents and more chemical data. Under the authority of the federal advisory committee act faca p. Sigmaaldrich offers a number of methanesulfonyl chloride products. Thermokinetic investigation of methanesulfonyl chloridewater. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Methanesulfonyl chloride is used as a reagent for conversion of alcohols to mesylate esters such as methanesulfonate, which is an intermediate in substitution reactions, elimination reactions, reductions. Sds of methanesulfonyl chloride, safety data sheets, cas. Methanesulfonyl chlorided 3 was obtained in 52% yield, and a small amount of dimethyl sulfoned 6 was also isolated. Synthesis of methanesulfonyl chloride msc from methane.
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